Isolation of pseudocapacitive surface processes at monolayer MXene flakes reveals delocalized charging mechanism

  • Journal: nature communications
  • Published Year: 2023
  • Authors: Marc Brunet Cabré, Dahnan Spurling, Pietro Martinuz, Mariangela Longhi, Christian Schröder, Hugo Nolan, Valeria Nicolosi, Paula E. Colavita & Kim McKelvey
  • Application: High-Performance Supercapacitors, energy storage, Device Fabrication, electrochemistry 

 

 

Summary

In this nature communications paper from Trinity College Dublin, researchers demonstrate a novel method to deconvolute the in-plane and out-of-plane electrochemical properties of MXenes, a promising material for energy storage applications. Using scanning electrochemical cell microscopy (SECCM) on Park’s NX10, they were able to pinpoint the electrochemical response of transition metal carbide Mxenes at length scales of 300 nm2, and in doing so uncovered evidence for rapid proton migration across MXene interfaces.  

 


This work reframes the understanding of pseudocapacitance in MXenes, emphasizing surface proton dynamics as dominant, and paving the way for faster, leaner, and more controllable energy storage devices.

 

 

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